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www.pharmacyexam.com                                                                  Krisman

            Atomic mass is designated by the symbol “A.” It is                n =   molecular weight
            the  sum  of  protons  (P)  and  neutrons  (N).  The              empirical formula weight
            formula  that  represents  the  atomic  mass  and
            atomic number is defined as:                                 n = 116/58 = 2
                                                                    Therefore, the molecular formula should be:
                        
                     

            Where,                                                       (C 3H 6O) 2  or C 6H 12O 2

            A = Mass number = P + N                               1231.(d) The molarity of the solution is defined as
            Z = Atomic number = P or Electron (E)                 the number of moles of solute per 1000 ml or 1 liter
            X = Element                                           of the solution. Therefore,

                                                                  1 M solution = 84 gm NaHCO 3  in 1000 ml
            A = Z + N                                             1               84
            63 = Z + 35                                           2  (0.5)M solution =   (42) gm NaHCO 3  in 1000 ml
                                                                                   2
                                                                               42
            Z = 28                                                0.5 M solution =   (10.5) gm NaHCO 3  in  1000  (250) ml
                                                                                4
                                                                                                    4

            Therefore,  the  atomic  number  for  Ni  is  28,  28   1232. (d)  According  to  Boyle’s  Law,  at  a  constant
            protons (P), 35 neutrons (N) and 28 electrons (E).    temperature  the  volume  of  gas  is  inversely
                                                                  proportional  to  its  pressure.  It  is  described  as

            1228. (b)  The  molecular  weight  of  methanol       follows:

            (CH 3OH) is 32 grams/mole. Therefore the number of
            moles present in 20 grams of methanol should be:             V = K / P where,


                    Weight in grams                                      V = Volume
            Moles  =                                                     P = Pressure
                    Molecular weight
                                                                         K = Constant
                     20
            Moles =     = 0.625 moles                             If  at  the  initial  stage the gas  has  a volume  V   and
                     32                                                                                     1
                                                                  pressure  P   at  constant  temperature,  and  may
                                                                            1
            1229. (c)  The  empirical  formula  represents  the   change to volume V  and pressure P  after time ‘t’
                                                                                    2              2
            lowest  whole  number  ratio  among  the  atoms  of   at  constant  temperature,  we  can  rewrite  the
            compounds.  Therefore,  divide  by  the  smaller      equation as:
            number:
                                                                         P V  = P V
                   Sn:  (0.664/0.664) = 1                                 1 1   2 2

                   O:  (1.33/0.664) = 2                                  P  = P V  / V
                                                                          2   1 1   2
            Therefore, the empirical formula should be SnO 2.                = 2 x 100 / 200
                                                                             = 1 atm = 760 mm Hg
            1230. (b) The empirical formula of the compound is
            C 3H 6O.  Therefore,  the  empirical  formula  weight  of   1233. (c) To solve this problem, we should use the
            the compound is:                                      following equation:

                                                                  P V       P V
                                                                   1 1
                   = (3 x C) + (6 x H) + (1 x O)                     T1     =     2 2
                                                                             T2
                   = (3 x 12) + (6 x 1) + (1 x 16)
                   = 58                                           Where,



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