Page 52 - Fpgee Question And Answer 2024 Edition
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                                   Atomic weight                                      0.75
            Equivalent weight =
                                Number of valence                 Equivalents of KCl =  74.5

                                27
            Equivalent weight =   = 9gm/Eq
                                 3                                Equivalents of KCl = 0.01006

            1239.  (c)  Mole  fraction  is  used  frequently  in   Milliequivalents of KCl = Equivalents x 1000
            experimentation involving theoretical consideration
            since it gives a measure of the relative proportion of   Milliequivalents of KCl = 0.01006 x 1000
            moles  of  each  constituent  in  a  solution.  It  can  be
            calculated as follows:                                Milliequivalents of KCl = 10.06 mEqs

                                                                                              +
                                     grams of FeSO  4             10.06 mEqs KCl = 10.06 mEqs K  = 10.06 mEqs Cl   -
                   Moles of FeSO     = Molecular weight
                                 4
                                                                  1243. (b)  The  volume  of  gas  can  be  found  by  the
                                     grams of CaCl  2
                   Moles of CaCl     =  Molecular weight          following formula:
                                2

                                     15.1                         P1V1   =   P2V2
                   Moles of FeSO     =  151   = 0.1 moles            T1           T2
                                 4

                             11.1
            Moles of CaCl     =   = 0.1 moles                     V2     = P1 x V1 x T2
                         2
                             111                                                  P2 x T1


            Mole Fraction of FeSO =       Moles of FeSO 4                = 710 x 50 x (273 +0)
                                4
                                    Moles of FeSO 4  + Moles of CaCl 2
                                                                                      760 x (273 +25)
                                      0.1
            Mole Fraction of FeSO =        = 0.5
                                4
                                    0.1 + 0.1                            =   42.79 cc

            1240.(b) 500 cc of 5% Dextrose solution contains:
                                                                  1244. (c)  The  calculation  of  molar  gas  constant  R
            500 x 5 = 25 grams of dextrose                        can be calculated by:
               100
                                                                  PV = nRT where

            1241.(b) 250 mg (0.25 gm) of cefazolin powder are
            diluted with water up to the 250cc mark. To find out   P = 760 mm Hg = 1 atm
                                                                  V = 22.4 liters
            the % of drug in the final solution:
                                                                  n   = 1 mole
            = 100 x 0.25   = 0.1%                                 R = ?                   o
                     250                                          T = (273.16 + 0) = 273.16 K

                                                                                                    o
                                                                  R =   1 x 22.4    =   0.082 atm lit/mole K
            1242. (c) An equivalent weight of KCl is:
                                                                           1 x 273.16
                                 Molecular weight
            Equivalent weight =                                   1245.(c) 74.07 liters.
                                Number of valence

                                74.5                              PV = nRT where:
            Equivalent weight =
                                  1
                                                                  P = 740/760 atm
                                 Weight in gram                   V =?
            Equivalents of KCl =
                                Equivalent weight                 n   = 3 moles
                                                                  R = 0.08205 lit atm / mole degK

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